DELOACH BLOG

Many types of water treatment systems depend on some type of media to provide the best performance required as it relates to water treatment and waste water treatment. For use in reverse osmosis there is a reliance on membranes which act as filters to separate the solids from the water. For ion exchange there are “resins” whether AION or CATION the resins works to treat hard and corrosive water. Degasification and decarbonation towers both require an internal media and sometimes this is referred to as “Random Packing” or “Loose Fill Media” and in this process the media acts like a traffic cop directing traffic.

In this case it directs the water on its way down and through a towers internals where it is constantly reshaping the water droplets over and over again forcing gas molecules to come to the surface edge of the water where they are removed. Carbon filters also require a media which is of course “Carbon”. The carbon media acts like a sponge absorbing the contaminants that you wish to remove from the water until it is saturated and must be replaced or regenerated. Even sand filters or pressure filters require a media.

What is the best process for hydrogen sulfide treatment? Biological odor control Scrubber or a Chemical Scrubber?

Most industrial water treatment, municipalities, and private customers are responsible for water and wastewater treatment and often generate "hydrogen sulfide" off-gas odors. Professionals who either provide the design engineering or maintain the water or wastewater collection systems need to address and control "hydrogen sulfide" odors. They often find themselves in a situation where they must select what type of odor control system will perform for their customer or at their location. A chemical odor control scrubber may utilize "chlorine" or "caustic" as a scrubbing agent or just "caustic" alone. Typically, "acids" are not used when treating "hydrogen sulfide" gas, but "acid. " Acid is used when treating other types of off-gases such as ammonia. The application or process, including incorporating "artificial intelligence" into the machinery to provide more rapid responses to operators to predict maintenance and other operational functions—treating process air generated by either a "decarbonation" tower or a "degasification" tower for the removal of "carbon dioxide (CO2) or "hydrogen sulfide (H2S). It is important to understand the basics of either of the processes to allow the design professional to properly select the best type of "odor control" scrubber to utilize and make the decision to either select a chemical scrubber that uses "caustic" or "chlorine" or a biological scrubber for the treatment of the hydrogen sulfide that only requires the use of "caustic" to buffer the recirculation water. In other types of processes involving treatment, such as ion exchange, a design professional or owner must understand that the process may also produce an off-gas that requires treatment. "Ion exchange" can be used as a standalone treatment process to treat hard water utilized as a post-treatment process after reverse osmosis. Regardless of when "ion exchange" is utilized, we recommend removing the carbon dioxide (CO2) before the process to prevent the formation of carbonic "acid" and to extend and save the life of the Ion Exchange resin. It may also be necessary to adjust the pH of the water either pre or post-treatment by injecting either an "acid" solution when lowering the pH or injecting a "caustic" solution when raising the ph. It is important to remember that the efficiency of the process depends on proper pH control.

High pH and hydrogen sulfide will not convert or be removed by “degasification” and the “carbon dioxide” cannot be removed.

Protecting Your Pharmaceutical Water: Ensuring Quality and Efficiency in Water Treatment

In the pharmaceutical industry, the removal of dissolved gases from water is a critical step in the water treatment process. However, it is essential to select the appropriate method of removing these gases, as the wrong choice can have detrimental effects on vital process water equipment such as steam boilers and distillation columns. Failure to address high levels of carbon dioxide (CO2) in the water can lead to the formation of carbonic acid, which corrodes and damages both the steam boiler tubes and distillation columns. To mitigate these risks, the implementation of a degasification tower or "Degasifier" is crucial, as it effectively removes dissolved gases like hydrogen sulfide (H2S) and carbon dioxide (CO2) to acceptable levels below 7 parts per billion (ppb).

Utilizing a degasification tower offers a cost-effective solution to reduce and eliminate gases in the water stream. In comparison, alternative methods such as reverse osmosis (RO) membranes require additional steps, including pH adjustment, to achieve similar results. The conversion of carbon dioxide (CO2) into carbonates can result in increased membrane fouling and elevated capital costs for the RO system. By implementing a degasification system, businesses can achieve optimal performance, minimize membrane fouling, and benefit from cost savings in both capital and operational expenses.

Water treatment towers and storage tanks are high places that require special precautions when entering. While the majority of people who enter these locations for work can be trusted, there are some hazards that make it more important than usual to follow safety procedures.

These locations can get very hot and humid, and can also be filled with harmful chemicals and microorganisms that can cause serious health issues if inhaled or absorbed through the skin. Therefore, the general standard for workplace safety is much higher when entering locations like these.

Make sure you have read and understood the following information about safety when entering a water treatment plant. It will help you understand how to stay safe and protect yourself from harm when entering a water treatment plant. normal installation, maintenance, or even emergency repairs, it is often required to enter into a water treatment tower (degasifier, air stripper, decarbonator, or clear well/ storage tank). When this occurs, full safety protocols should be followed at all times, in accordance with OSHA regulations.  A tower or tank B classification is a "Confined Space" location. For more information visit the OSHA combined space regulations page.

In addition, there are other safety risks that an operator or technician can be exposed to while inside these types of closed locations. The risk can come from fumes of hydrogen sulfide (H2S), chlorine from an injection line, or a lack of oxygen O2. A proper confined space permit should be prepared and only technicians with proper training and certifications should enter into these types of confined spaces.

CO2 & pH In municipal and industrial water processes

Carbon Dioxide (CO2) in municipal and Industrial water can create problems in the water treatment process, increase operational costs of the treatment plant, and cause excessive corrosion to equipment and ancillary equipment.

In nature, one of the most natural common causes that create low pH or acidity in water is an element known as “Carbon Dioxide” (CO₂).  The process of how carbon dioxide enters the water in the first place is a topic worth exploring.  Nature creates one of the most common causes of CO₂ found in the water naturally. When the water reaches an equilibrium with our atmosphere followed by the biological degradation that is aided by the photosynthesis of organic carbon (CH₂O) then carbon dioxide begins to form. Organic carbon is dissolved in water and it forms “Carbonic Acid”

(H₂CO₃).  CO_{2 (g)} + H₂O _(l) = H₂CO_3 (aq). 

The process to form the carbonic acid is slow and only a small portion remains as an acid because proton losses occur during the process.

H₂CO₃ (aq) « H⁺ (aq) + HCO₃^- (aq)

CO₃^- (aq) « H⁺ (aq) + CO₃^2- (aq)