Requires an application commonly referred to as either “Degasification” or "Decarbonation" and it requires the use of a piece of water treatment equipment called either a “degasifier” or a “decarbonator”.
Both of these are similar in nature and are designed for Carbon Dioxide (CO2) removal from the incoming water. A properly designed decarbonator can remove 99.99% of the free carbon dioxide gas that is present in the water stream. One of the primary reasons for utilizing a decarbonator or degasifier for the removal of carbon dioxide gas is the raise the pH of the water without the need to add caustic. resulting in high-purity water.
The other reason is the remove the CO2 prior to treating the water with Ion Exchange which utilizes Anion or Cation resins to reduce the regeneration cycles for the resin beds. High concentrations of CO2 consume the ion charge within the resins and require more frequent regeneration cycles. The difference between anion and cation resins is that one is positively charged (anion) and the other is negatively charged (cation), cation resins, attract positive ions with their negative charge.
The term decarbonation describes the process of the removal of suspended gas or the conversion of carbonic acids into free Carbon Dioxide. Carbonic Acid (H2CO3) is stable at normal ambient anhydrous conditions. However, Carbonic Acid decomposes when not stable and in the presence of any water molecules to form carbon dioxide (CO2). The Carbonic acid breaks down when present in water and it is converted to a gas based upon certain conditions. It is common to have CO2 present in water requiring a decarbonation process when utilizing certain types of water filtration such as membrane filtration with reverse osmosis or it can be present when the need to adjust pH is required. When removing (CO2) the process is often referred to as “Decarbonation”, when removing (H2S) Hydrogen Sulfide the process is often referred to as “Degasification”.
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Topics:
water treatment issues,
degasification,
pH levels of water,
aeration,
iron oxidation,
water treatment,
water plant,
bicarbonate,
hydrogen sulfide (H2S),
pH levels,
Decarbonation,
ION Exchange Resin,
dissolved gases,
De-Aeration,
wastewater,
carbon dioxide,
oxygen,
decarbonator,
degasifier,
gases,
carbonic acid,
H2S Degasifier
The Basics of Water Decarbonation
and the removal of carbon dioxide (CO2). The need to remove (CO2) is essential in most Aquaculture, Municipal, Industrial, and Food & Beverage Processes To understand you must familiarize yourself with Henry’s Law.
Henry's Law defines the method and proportional relationship between the amount of a gas in a solution in relation to the gas's partial pressure in the atmosphere. Often you will see and hear various terms like degasification, decarbonation, aeration, and even air stripping when discussing the removal of dissolved gases and other convertible elements from water. Understanding the impacts that Carbon Dioxide (CO2) can have on both equipment and aquatic life provides the basic reasons why the need to decarbonate water, exists. Carbon Dioxide (CO2) can exist naturally in the raw water supply or be the result of ph control and balance. In either case, the process called Decarbonation or Degasification provides the most cost-effective and efficient manner to reduce or tally remove (CO2) from the water. In addition to Carbon Dioxide (CO2), water can contain a variety of other contaminants that may impact the removal efficiency of the Carbon Dioxide. A variety of elements as well as dissolved gases such as oxygen, nitrogen, and carbon dioxide (CO2). A full analytical review of the water chemistry is required to properly design and size the “Water Treatment” process.
Breaking the bonds in water releases a dissolved gas
such as carbon dioxide (CO2) you must change the conditions of the vapor pressure surrounding the gas and allow the gas to be removed. There are many variables to consider when designing or calculating the “means and methods” of the removal of carbon dioxide (CO2). When I refer to the means and methods. I am referring to the design of a decarbonator and its components. The means equals the size and type (Hydraulic load) of the decarbonator and the “method” equals the additional variables such as the cubic foot of airflow (CFM) and “Ratio” of the air to water to accomplish the proportional condition needed to remove the carbon dioxide (CO2).
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Topics:
water treatment issues,
degasification,
pH levels of water,
aeration,
iron oxidation,
water treatment,
water plant,
bicarbonate,
hydrogen sulfide (H2S),
pH levels,
Decarbonation,
ION Exchange Resin,
dissolved gases,
De-Aeration,
wastewater,
carbon dioxide,
oxygen,
degasifier,
gases,
carbonic acid,
H2S Degasifier,
removal of CO2 from water
In many water treatment and chemical processes,
it is a requirement to keep track of the pH of the water or product stream. In DeLoach Industries equipment such as degasification systems, or odor control scrubbers, pH measurement is critical to control the chemical reactions happening within the treatment system. PH is an indication of the acidic vs alkaline nature of the fluid. An acidic fluid will have a greater concentration of H+ hydrogen ions, while an alkaline fluid will have a greater concentration of OH- hydroxide ions. This electrochemical nature is used in the construction, reading, and maintenance of electronic pH probes.
PH probes are generally glass and will contain a reference element, and a sensing element. When the pH probe is immersed in the fluid to be measured, the electrical potential difference between the sensing element and the reference element is amplified by electronics and the resulting voltage is used in a calculation to determine pH from differential electron potential. As a pH probe remains in service, ion exchange will slowly change the electrical potential of the sensing element, the reference element, or both. This happens because the hydrogen ions are small enough to travel through the glass sensor body and cause reference potential shifts over time. This is normal behavior for all pH probes and is the reason why pH probes must be periodically calibrated.
Calibration is a process where a pH probe is immersed in a series of standardized stable pH solutions called “buffers”. The standard set of buffers includes a pH 4.0 acidic buffer, a pH 7.0 neutral buffer, and a pH 10.0 alkaline buffer. These buffer solutions are chemically designed to hold a stable pH and are used as a reference for the internal calculations that are done by the pH amplifier or transmitter that interprets the reading taken by the pH probe. As the reference voltage vs actual pH for a mature probe changes, the known buffer solution provides a benchmark for the calculation. Each pH instrumentation manufacturer will have a slightly different method for performing a calibration, but in general, the system will have you step through the buffer solutions while an automated routine makes note of the expected voltage vs calibration voltage at each step. The computation algorithm will use this drift information to re-scale the calculation to re-establish accuracy.
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Topics:
water treatment issues,
water quality,
pH levels of water,
iron oxidation,
water treatment,
advanced treatment solutions,
hydrogen sulfide (H2S),
pH levels,
Alkalinity,
ION Exchange Resin,
carbon dioxide,
gases,
RO system,
Aqua Farming
The need to remove harmful water elements, such as Hydrogen Sulfide H2s and Carbon Dioxide CO2, from water in the pisciculture and aquaculture market is extremely important.
To achieve maximum results, the industry utilizes a treatment technology called “Degasification” and controls the pH precisely to maximize results. When utilizing equipment such as the DeLoach Industries degasification systems, the hydrogen sulfide, and carbon dioxide levels can be removed to 99.999% ug/l.
pH control with water degasification in water treatment is very important for aquaculture and the pisciculture market. In addition, there are a host of other organic and inorganic elements found in water, both naturally occurring and manmade, that require removal during some part of the water treatment process, and pH plays a significant role in the effectiveness of the treatment process.
Every application of degasification depends on pH adjustment to maximize results. As an example, the treatment of water may require the removal of hydrogen sulfide (H2S) to protect the species during the growth period. Hydrogen sulfide can be removed either as a “free” gas or requires the conversion of sulfides into (H2S) as a gas. You will often also see the need to adjust the pH of the water chemistry to maximize both the removal and the conversion to increase the efficiency of the equipment utilized to remove the hydrogen sulfide, such as a degasification tower or a degasifier.
Why is pH important, and what it means in water?
Water pH is a term used to describe whether or not the water is “acidic” or “basic.” pH ranges in water can be from 0-14. 0 is the most acidic, and 14 is at the far end and is the most basic, leaving “7” as the neutral state. A pH of 7 is neither acidic nor basic. So, what causes pH to be acidic? In nature, the most common cause of a low acidic pH in water is carbon dioxide (CO2) which occurs naturally when photosynthesis, decomposition, or respiration occurs in nature. The increase in CO2 causes an increase in ions, producing a lower pH in a simplified explanation.
How does pH play such a significant role in Aquaculture and Pisciculture?
Removing certain harmful elements is typically required to safeguard the growth of most aquatic species, and elements such as sulfides, sulfates, and free H2S hydrogen sulfide gases are dangerous. They can often kill many types of aquatic life. To maximize the removal of hydrogen sulfide from water utilizing a DeLoach Industries degasification tower, it is important to maintain as close to a pH of 5 as possible. When the pH rises above 5, the ability to convert and strip the free H2S gas from the water diminishes. When a degasification tower operates within this specific range and if it has been designed with the higher efficient distribution systems such as the ones utilized by DeLoach Industries, removal efficiencies of 99.999%- 100% can be achieved. If the pH rises to 7 or above, the removal process becomes much more difficult, and typically you will have much lower results. The pH adjustment during the water treatment process is normally accomplished by adding commercially available acid, such as “Sulphuric Acid,” one of the most common within the municipal and food and beverage industry.
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Topics:
water treatment issues,
water quality,
degasification,
pH levels of water,
water treatment,
advanced treatment solutions,
hydrogen sulfide (H2S),
pH levels,
Decarbonation,
carbon dioxide,
oxygen,
decarbonator,
degasifier,
H2S Degasifier,
Aqua Farming,
Fish Farming,
Aquaculture,
Pisciculture
The need for pH control with water degasification and decarbonation in water treatment includes almost every industry and includes;
The need for pH control with water degasification and decarbonation in water treatment includes almost every industry and including; Aquaculture, food, and beverage, industrial, municipal, and even pisciculture. In some water treatment applications, harmful gases such as Hydrogen Sulfide (H2S) are removed, while in other applications, Carbon Dioxide (CO2) or a combination of both. In addition, there's a host of other organic and inorganic elements found in water, both naturally occurring and manmade, that require removal during some part of the water treatment process.
In almost every application of degasification or decarbonation, you will hear or see the term pH used either by need or by the result. If, as an example, the water treatment application requires the removal of Hydrogen Sulfide (H2S) to be removed either as “free” gas or requires the conversion of Sulfides into (H2S) gas. You will often also see the need to adjust the pH of the water chemistry to maximize both the removal and the conversion to increase the efficiency of the equipment being utilized to remove the hydrogen sulfide, such as a degasification tower or commonly called a degasifier.
So, what is pH?
Water pH is a term used to describe whether or not the water is “acidic” or “basic.” pH ranges in water can be from 0-14. 0 is the most acidic, and 14 is at the far end and is the most basic, leaving “7” as the neutral state. A pH of 7 is neither acidic nor basic. So, what causes pH to be acidic? In nature, the most common cause of a low acidic pH in water is Carbon Dioxide (CO2) which occurs naturally when photosynthesis, decomposition, or respiration occurs in nature. The increase in CO2 causes an increase in ions, producing a lower pH in a simplified explanation.
How does pH play such a significant role in degasification and decarbonation?
As mentioned above in the example of the removal of certain harmful elements such as sulfides, sulfates, and free H2S hydrogen sulfide gases, to maximize the removal from water utilizing a degasification tower, it is essential to maintain as close to a pH of 5 as possible. When the pH rises above 5, the ability to convert and strip the free H2S gas from the water diminishes. When a degasification tower operates within this specific range and if it has been designed with the higher efficient distribution systems such as the ones utilized by DeLoach Industries, removal efficiencies of 99.999%- 100% can be achieved. If the pH rises to seven or above, the removal process becomes much more complex, and typically, you will have much lower results. The pH adjustment during the water treatment process is typically accomplished by adding commercially available acid, such as “sulphuric acid,” one of the most common in the municipal and food and beverage industry.
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Topics:
water treatment issues,
water quality,
degasification,
pH levels of water,
odor control,
water treatment,
advanced treatment solutions,
hydrogen sulfide (H2S),
Chemical Odor,
pH levels,
Decarbonation,
dissolved gases,
carbon dioxide,
degasifier,
gases,
H2S Degasifier,
Aqua Farming,
Fish Farming,
Aquaculture
Optimizing Water Quality and Enhancing Efficiency.
To enhance and balance the water quality in aquaculture and pisciculture operations, the industry is recognizing the benefits of utilizing a type of water treatment called “Forced Draft Degasification” to remove CO2 (Carbon Dioxide) and H2S (Hydrogen Sulfide) gases and oxidize other elements such as Iron or Magnesium.
Removing these elements from the water process improves the quality of the water and aids in the balancing of the pH without the need for additional chemicals. This also reduces the risk of unnecessary and preventable loss of life to your aqua farming project. Keeping the ph at the proper level will enable a good healthy environment and will prevent further problems that may occur due to the ph is not kept in a stable state.
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Topics:
De-Aeration,
carbon dioxide,
decarbonator,
degasifier,
gases,
H2S Degasifier,
Aqua Farming,
Fish Farming,
Aquaculture,
Pisciculture
Basics of water decarbonation for dissolved organic carbon.
The water treatment industry continues to develop and evolve. Over the past two decades, there have been many new developments in technology and even more refinement in existing technologies such as "Degasification". The evolution and advancement of water treatment have been driven by the constantly increasing demand from an increase in population that demand cost-effective solutions and recognition to improve safety with the implementation of NSF 61 standards.
All human cultures on our planet share a single commonality: the dependency on water to survive.
Many existing technologies, such as "Degasification," have evolved with higher efficiency to meet the demand changes and provide safety to consumers and the systems. Degasification refers to the removal of dissolved gases from liquids, and the science to degasify water is based upon a chemistry equation known as "Henry's Law". The "proportionality factor" is called Henry's law constant" and was developed by William Henry in the early 19th century. Henry's Law states that "the amount of dissolved gas is proportional to its partial pressure in the gas." The most "cost" effective method to perform degasification is with the packed vertical tower called a "Degasifier” or “Decarbonator.”
The key words in this previous sentence for owners, operators, and engineers to focus on is "the most cost-effective" as there is no other process more cost-effective at removing dissolved gases at the lowest cost than using a Degasifier or decarbonator. The process of degasification is simple enough to understand. Water is pumped to the top of a vertically constructed tower, where it first enters the tower through some type of distribution system at the same time, there is a cross-current air flowing up from the bottom by a blower located at the bottom of the tower, and the air encounters the water and is exhausted at the top of the tower through an exhaust port. There are various types of distribution systems, and we will explore these in later discussions. Once the water enters the top of the tower and passes through the distribution system, it then travels by gravity downward. The next thing the water encounters is some type of media packing. There are various forms of media packing offered in the degasification industry, and each type can offer higher performance or have the ability to deter fouling. The selection of the type, size, and volume is where the “experience, engineering, and understanding of each application” comes into play.
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Topics:
water treatment issues,
water quality,
degasification,
pH levels of water,
water treatment,
advanced treatment solutions,
About DeLoach Industries,
water plant,
NSF/ANSI 61,
hydrogen sulfide (H2S),
media packing,
pH levels,
scaling,
caustic,
Decarbonation,
Safe drinking water,
dissolved gases,
carbon dioxide,
decarbonator,
boiler system,
degasifier,
carbonic acid,
H2S Degasifier,
Dissolved organic Carbon,
co2 dissolved in water
In the production and purification of water for industry
there are many types of different processes available to remove harmful minerals and gases from the water stream but the most effective process and most cost-effective from both a capital investment and operational cost is a “Forced Draft Degasification System” (Degasifier).
Degasification is used in a wide range of water processes for industrial and municipal applications which extend from the production of chemicals to the production of semiconductors and in all applications the need to remove contaminants from the water and dissolved gases is key to achieving the end results needed in the industrial water process. Water from the ground often contains elements such as calcium carbonate, manganese, iron, salts, hydrogen sulfide, and sulfur just to name a few of the basic contaminants and these naturally occurring elements can cause serious damage and consequences to process equipment such as boiler systems, piping, membranes, and cation and anion exchange resins used in the demineralization process.
Calcium carbonate can dissolve in water under certain pH ranges forming carbonic acid and releasing carbon dioxide (CO2) gases. These gases are not only very corrosive to equipment like boiler feed systems and boiler tubes but also attack the actual resin beds found in cation and anion softening and demineralization system causing an increase in regeneration and chemical consumption and resin bed replacement.
By incorporating a Force Draft Degasification system you can remove dissolved gasses
like CO2 and hydrogen sulfide (H2S) to as low as 99.999% and improve the cation and anion system performance, extend the resin bed life, and lower the operating cost of the water treatment process.
Quite often Forced Draft Degasification is utilized “post” treatment to also remove newly formed dissolved gases prior to entering the boiler feed system to prevent corrosion damage within the tubes and feed system and pumps. These gases are easily removed with the forced draft degasifier at a much lower cost than chemical additives or liquid cell degasification that requires higher capital cost and much higher operating cost.
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Topics:
water treatment issues,
degasification,
pH levels of water,
iron oxidation,
water treatment,
water distribution system,
aluminum,
water plant,
odor control scrubber,
hydrogen sulfide (H2S),
calcium carbonate,
media packing,
pH levels,
Langilier index (LSI),
Decarbonation,
ION Exchange Resin,
dissolved gases,
feed water,
De-Aeration,
wastewater,
carbon dioxide,
decarbonator,
degasifier,
carbonic acid,
H2S Degasifier
To enhance and control the production and quality of seafood grown and harvested.
The industry increasingly focuses on constructing in-house aquaculture fish farms, commonly called aqua farming. The most popular species of aqua farming continue to be salmon, tilapia, catfish, and carp. Increased interest in the United States has developed aqua farming facilities in southern Florida with favorable climate and water conditions.
When considering several types of fish species to grow for harvest, it is important to remember the need to control the water quality. If the aqua farm is intended to utilize man-made tanks, they will depend upon a constant flow of incoming water. If the aqua farm focuses on salmon, the water quality and temperature play a major role in the operation's mortality rates and production yields.
Having water with too high of hydrogen sulfide, carbon dioxide, total Organic carbons, and even turbidity can increase mortality rates among the younger fish species and is especially critical to salmon.
Having high levels of metals
Such as Iron that is identified as either “ferric” (Fe-) or “ferrous” (FE+2) and is naturally occurring within the Florida waters and other parts of the US will cause significant damage to young salmon species because the metal accumulates within the gills of the fish causing suffocation. Other metals are also detrimental to fish, including copper, aluminum, arsenic, cadmium, chromium, Lead, manganese, and mercury, to name a few, and the water quality must be evaluated and tested in the early stages of design to anticipate the required types of process systems needed.
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Topics:
water treatment issues,
water quality,
degasification,
pH levels of water,
water treatment,
advanced treatment solutions,
hydrogen sulfide (H2S),
pH levels,
Alkalinity,
Decarbonation,
carbon dioxide,
oxygen,
decarbonator,
degasifier,
carbonic acid,
H2S Degasifier,
Aqua Farming,
Fish Farming,
Aquaculture,
Pisciculture
Water Treatment
When planning and designing a man made on land aquaculture or pisciculture facility.
The most important key element is the quality of the water. For operations developing in Florida or the Caribbean it is important to remember that water quality varies in Florida and other states in the US and typically requires some type of water treatment. For fresh and salt water land based farms that utilize tanks located inside of a building the water needs to be treated and pure from any naturally occurring contaminants such as hydrogen sulfide (H2S), iron (Fe+), and even carbon dioxide (CO2).
The most cost effective way to treat incoming water for aquaculture farming and remove hydrogen sulfide, iron, and lower carbon dioxide is the use of a “degasification” tower. A degasification tower or degasifier is a piece of process equipment. Degasifiers can also be referred to as a “decarbonator” or “air stripper” or even “aeration tower”. The degasification tower is a vertical column designed to remove certain types of contaminants by “stripping” the molecules of converted gases and expelling them from the water as a gas. The science is based upon “Henry’s Law” and it relies upon the disproportionate varying vapor pressures of gases.
If the incoming raw water contains levels of sulfides or hydrogen sulfide gases it is recommended to remove the hydrogen sulfide to improve the water quality and reduce the risk of the development and formation of bacteria that can thrive on the Sulfur. In addition hydrogen sulfide is corrosive and will cause harm to other components within the process if left untreated. It is important to adjust the pH of the raw feed water prior to degasification to ensure full conversion of the sulfides into hydrogen sulfide gas (H2S) to enable the degasification process to perform and remove up to 99.99% of the harmful contaminants without adding additional chemicals. This saves money and improves quality of the product!
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Topics:
water quality,
degasification,
pH levels of water,
water treatment,
hydrogen sulfide (H2S),
pH levels,
Alkalinity,
Decarbonation,
Caribbean,
carbon dioxide,
decarbonator,
degasifier,
gases,
carbonic acid,
H2S Degasifier,
Aqua Farming,
Fish Farming,
Aquaculture,
Pisciculture