DELOACH BLOG

Ammonia (AM) is a common water pollutant that significantly impacts the water process industry.

It is not just polluting water bodies but also aqua wells and humidifiers. Generally, AM is produced from human sweat and urine and created from synthetic ammonia in industrial processes.

Ammonia has three types of amines – primary, secondary, and tertiary – all are toxic for humans and aquatic life.

• Primary Amine has two carbon and one nitrogen atom, also called methylamine or CHNH2.
• Secondary Amine has two nitrogen atoms with no carbon atom between them, also called Dimethylamine or CH2(NH)CH3.
• Tertiary Amine has three nitrogen atoms with no carbon atoms between them; thus, it’s called Trimethylamine or CH3C(NH)CH3.

In natural conditions, primary Amide bacteria produce Amide under high-temperature conditions. In an aqueous solution and soil environments with high pH levels (>6).

Primary amide can form by the dehydrogenation of nitriles, such as acetonitrile, which are further oxidized to form acetic acid. 

Primary amide form by alkaline hydrolysis of nitro compounds such as 2-nitrophenol.

Process systems often need to recognize when the Degasification or Decarbonation system is failing or underperforming.

Understanding De-Aeration and Decarbonation in Water Treatment Systems

Protecting Your Pharmaceutical Water: Ensuring Quality and Efficiency in Water Treatment

In the pharmaceutical industry, the removal of dissolved gases from water is a critical step in the water treatment process. However, it is essential to select the appropriate method of removing these gases, as the wrong choice can have detrimental effects on vital process water equipment such as steam boilers and distillation columns. Failure to address high levels of carbon dioxide (CO2) in the water can lead to the formation of carbonic acid, which corrodes and damages both the steam boiler tubes and distillation columns. To mitigate these risks, the implementation of a degasification tower or "Degasifier" is crucial, as it effectively removes dissolved gases like hydrogen sulfide (H2S) and carbon dioxide (CO2) to acceptable levels below 7 parts per billion (ppb).

Utilizing a degasification tower offers a cost-effective solution to reduce and eliminate gases in the water stream. In comparison, alternative methods such as reverse osmosis (RO) membranes require additional steps, including pH adjustment, to achieve similar results. The conversion of carbon dioxide (CO2) into carbonates can result in increased membrane fouling and elevated capital costs for the RO system. By implementing a degasification system, businesses can achieve optimal performance, minimize membrane fouling, and benefit from cost savings in both capital and operational expenses.

The importance of removing Carbon Dioxide in the water!

Carbon dioxide exists naturally in nature as free CO2 and can be found in many water sources from lakes, streams, or other surface water bodies. Carbon dioxide occurs naturally in small amounts (about 0.04 percent) in the Earth's atmosphere. Monitoring CO2 levels in your water can be done through test kits or monitoring systems. When monitoring CO2 levels, it is important to note the concentration at which the monitoring needs to occur. Industrial level ion exchange systems should be monitored at a concentration typically 15–20 times greater than required for drinking water quality. Ion exchange systems used for high purity water production should be monitored at a concentration typically 40–50 times greater than what is required for drinking water quality. Due to carbon dioxide’s abundance and its role as the primary driver of climate change, there are concerns about increasing concentrations of this gas in the atmosphere. To reduce the amount of carbon dioxide in the atmosphere, people can reduce the amount of carbon dioxide released during energy production by using renewable energy sources and energy efficiency. Carbon dioxide can be captured and stored underground with carbon sequestration technologies.

Saving Steam with Degasification: Optimizing Water Treatment for Cost Efficiency and Enhanced Performance.

The operation of steam-generating boilers and the process of removing dissolved gases from the feed water is of utmost importance.

Deaeration is essential in the boiler system process.

Deaeration involves removing oxygen (O2) and carbon dioxide (CO2) from the water. Removing oxygen and carbon dioxide from the water before it enters the boiler system is essential. This prevents corrosion of the boiler system components and reduces costly maintenance and repairs to your system.

Oxygen and carbon dioxide can corrode and destroy metal components of the boiler system.

Corrosion can be costly to repair or replace. This is due to oxygen (O2) and carbon dioxide (CO2) not being removed from the water.

In order to avoid unwanted corrosion, it is necessary to treat the water before it enters the boiler system. This can be achieved through different techniques, including deaeration, chemical treatment, or mechanical filtration.

The deaeration process typically requires a deaerator. This device combines heat and vacuum to remove dissolved gases from water. The deaerator reduces the amount of dissolved solids in the water.This can improve the efficiency of the boiler system. Neglecting regular maintenance and inspection of the boiler can lead to severe corrosion damage and operational issues.

In the past two decades, there has been a remarkable development and improvement in wastewater technologies, driven by both necessity and stringent governmental regulations.

Today, municipalities and countries worldwide are recognizing the vital importance of recycling wastewater into clean drinking water. In certain regions like the Caribbean and other foreign nations, the wastewater to the drinking water industry is not merely a choice but a necessity.

To address our global needs and challenges, the recycling of wastewater to produce safe drinking water has become an everyday practice, empowered by cutting-edge technologies such as "Ultra-Filtration" and "Membrane Bio-Reactors" (MBR). These technologies continue to advance, offering much-needed solutions to the world's water scarcity issues. Moreover, due to stricter governmental requirements for wastewater recycling, the purity standards achieved through this process often surpass those of conventional water treatment methods. To foster global growth, it is crucial for professionals and consumers alike to acknowledge and embrace wastewater recycling whenever and wherever it is applicable to meet our evolving needs.

One of the key elements in the wastewater recycling process is the removal of contaminants, such as hydrogen sulfide gas, through advanced treatment methods. Hydrogen sulfide gas, a common byproduct of various industrial processes, can pose significant risks to water quality. Through technologies like Ultra-Filtration, this harmful gas can be effectively eliminated, ensuring the production of safe drinking water.

Another crucial aspect of wastewater treatment is addressing water turbidity. Turbidity refers to the cloudiness or haziness of water caused by the presence of suspended particles. By employing techniques like Membrane Bio-Reactors (MBR), wastewater can undergo thorough filtration, effectively removing suspended solids and improving water clarity. This ensures that the recycled water meets stringent purity standards and is suitable for drinking.

Water treatment in the Caribbean poses unique challenges due to the specific characteristics of the region.

Extending the life of your ion exchange resin in boiler feed water applications

Did you know that when producing steam, it is most effectively accomplished by utilizing a decarbonation process? Decarbonation and Degasification is the most economical way to process fluent water pre-Ion exchange treatment through a vertically packed tower called a decarbonator, often called a degasifier.  This is the most economical method to remove carbon dioxide (CO2) and Hydrogen Sulfide (H2S) to prevent the formation of carbonic acid. Other corrosive conditions are Degasification and Decarbonation, which will extend the life of the ion exchange resin. If CO2 levels remain high in the inlet feed water to the ion exchange system, the resin beds, whether cation or anion, will require more frequent regeneration, and your chemical usage and cost will rise.

In industrial applications, it’s easy to overlook.

Often, there is insufficient focus on selecting the right decarbonation or degasification system to ensure that the process water treatment system performs at the highest optimal level. For water filtration, when the primary process is membrane filtration, often referred to as “reverse osmosis, " too little attention is given to properly removing CO2 from the process to lower the pH and adjust the alkalinity.