DELOACH BLOG

In the production and purification of water for industry

there are many types of different processes available to remove harmful minerals and gases from the water stream but the most effective process and most cost-effective from both a capital investment and operational cost is a “Forced Draft Degasification System” (Degasifier).

Degasification is used in a wide range of water processes for industrial and municipal applications which extend from the production of chemicals to the production of semiconductors and in all applications the need to remove contaminants from the water and dissolved gases is key to achieving the end results needed in the industrial water process. Water from the ground often contains elements such as calcium carbonate, manganese, iron, salts, hydrogen sulfide, and sulfur just to name a few of the basic contaminants and these naturally occurring elements can cause serious damage and consequences to process equipment such as boiler systems, piping, membranes, and cation and anion exchange resins used in the demineralization process.

Calcium carbonate can dissolve in water under certain pH ranges forming carbonic acid and releasing carbon dioxide (CO2) gases. These gases are not only very corrosive to equipment like boiler feed systems and boiler tubes but also attack the actual resin beds found in cation and anion softening and demineralization system causing an increase in regeneration and chemical consumption and resin bed replacement.

By incorporating a Force Draft Degasification system you can remove dissolved gasses

like CO2 and hydrogen sulfide (H2S) to as low as 99.999% and improve the cation and anion system performance, extend the resin bed life, and lower the operating cost of the water treatment process.

Quite often Forced Draft Degasification is utilized “post” treatment to also remove newly formed dissolved gases prior to entering the boiler feed system to prevent corrosion damage within the tubes and feed system and pumps. These gases are easily removed with the forced draft degasifier at a much lower cost than chemical additives or liquid cell degasification that requires higher capital cost and much higher operating cost.

Topics: water treatment issues, degasification, pH levels of water, iron oxidation, water treatment, water distribution system, aluminum, water plant, odor control scrubber, hydrogen sulfide (H2S), calcium carbonate, media packing, pH levels, Langilier index (LSI), Decarbonation, ION Exchange Resin, dissolved gases, feed water, De-Aeration, wastewater, carbon dioxide, decarbonator, degasifier, carbonic acid, H2S Degasifier

To enhance and control the production and quality of seafood grown and harvested.

The industry increasingly focuses on constructing in-house aquaculture fish farms, commonly called aqua farming. The most popular species of aqua farming continue to be salmon, tilapia, catfish, and carp. Increased interest in the United States has developed aqua farming facilities in southern Florida with favorable climate and water conditions.

When considering several types of fish species to grow for harvest, it is important to remember the need to control the water quality. If the aqua farm is intended to utilize man-made tanks, they will depend upon a constant flow of incoming water. If the aqua farm focuses on salmon, the water quality and temperature play a major role in the operation's mortality rates and production yields.

Having water with too high of hydrogen sulfide, carbon dioxide, total Organic carbons, and even turbidity can increase mortality rates among the younger fish species and is especially critical to salmon.

Having high levels of metals

Such as Iron that is identified as either “ferric” (Fe-) or “ferrous” (FE+2) and is naturally occurring within the Florida waters and other parts of the US will cause significant damage to young salmon species because the metal accumulates within the gills of the fish causing suffocation. Other metals are also detrimental to fish, including copper, aluminum, arsenic, cadmium, chromium, Lead, manganese, and mercury, to name a few, and the water quality must be evaluated and tested in the early stages of design to anticipate the required types of process systems needed.

Topics: water treatment issues, water quality, degasification, pH levels of water, water treatment, advanced treatment solutions, hydrogen sulfide (H2S), pH levels, Alkalinity, Decarbonation, carbon dioxide, oxygen, decarbonator, degasifier, carbonic acid, H2S Degasifier, Aqua Farming, Fish Farming, Aquaculture, Pisciculture

Water Treatment

When planning and designing a man made on land aquaculture or pisciculture facility.

The most important key element is the quality of the water. For operations developing in Florida or the Caribbean it is important to remember that water quality varies in Florida and other states in the US and typically requires some type of water treatment. For fresh and salt water land based farms that utilize tanks located inside of a building the water needs to be treated and pure from any naturally occurring contaminants such as hydrogen sulfide (H2S), iron (Fe+), and even carbon dioxide (CO2).

The most cost effective way to treat incoming water for aquaculture farming and remove hydrogen sulfide, iron, and lower carbon dioxide is the use of a “degasification” tower. A degasification tower or degasifier is a piece of process equipment. Degasifiers can also be referred to as a “decarbonator” or “air stripper” or even “aeration tower”. The degasification tower is a vertical column designed to remove certain types of contaminants by “stripping” the molecules of converted gases and expelling them from the water as a gas. The science is based upon “Henry’s Law” and it relies upon the disproportionate varying vapor pressures of gases.

If the incoming raw water contains levels of sulfides or hydrogen sulfide gases it is recommended to remove the hydrogen sulfide to improve the water quality and reduce the risk of the development and formation of bacteria that can thrive on the Sulfur. In addition hydrogen sulfide is corrosive and will cause harm to other components within the process if left untreated. It is important to adjust the pH of the raw feed water prior to degasification to ensure full conversion of the sulfides into hydrogen sulfide gas (H2S) to enable the degasification process to perform and remove up to 99.99% of the harmful contaminants without adding additional chemicals. This saves money and improves quality of the product!

Topics: water quality, degasification, pH levels of water, water treatment, hydrogen sulfide (H2S), pH levels, Alkalinity, Decarbonation, Caribbean, carbon dioxide, decarbonator, degasifier, gases, carbonic acid, H2S Degasifier, Aqua Farming, Fish Farming, Aquaculture, Pisciculture

Treating Hydrogen Sulfide for Environmental Safety

Topics: odor control, aeration, water treatment, advanced treatment solutions, biological scrubber, water plant, odor control scrubber, hydrogen sulfide (H2S), Chemical Odor, pH levels, Decarbonation, dissolved gases, wastewater, carbon dioxide, degasifier, gases, Amine, H2S Degasifier

DeLoach Industries made history in 1977 at the City of Cape Coral Florida water treatment plant with its large scale “degasification towers” connected to what was to become the first municipal water treatment facility in the United States to deploy the use of reverse osmosis on a large-scale production municipal treatment plant.

The Cape Coral water treatment plant for came online in 1977 and produced 3 million gallons of water per day (GPD) or 11.35 liters of purified and treated water utilizing the “reverse osmosis” process. By 1985 the plant had expanded as it kept up with growth to produce 15 million gallons per day making it at the time the world’s largest “reverse osmosis” water treatment plant facility.

Topics: water quality, pH levels of water, water treatment, advanced treatment solutions, water plant, hydrogen sulfide (H2S), pH levels, Alkalinity, scaling, chlorine, caustic, Decarbonation, wastewater, carbon dioxide, degasifier, RO membrane, RO system, H2S Degasifier

A Biological Scrubber is a wet odor control scrubber that treats and removes contaminants from an air stream.

It utilizes caustic typically to control the pH of the re-circulation solution. There are several types of odor control and chemical fume scrubbers on the market today. Each plays a role in treating noxious or corrosive gases in the industry.

Biological scrubbers are used in municipal applications to treat low and high hydrogen sulfide (H2S) gas levels. This colorless gas is removed from the water or wastewater treatment process. 

Water treatment equipment such as “degasification” or “decarbonation” towers.

Strips the hydrogen sulfide gas from the treated wastewater and exhausts the gas from an exhaust port. These gases are captured and sent to the biological scrubber via an air duct system. The health effects of hydrogen sulfide can cause eye irritation, loss of appetite, and fluid in the lungs. Hydrogen gases are captured at a wastewater treatment process, including treatment facilities, lift stations, or head-works facilities. The PVC or FRP duct system sends the gases to the biological scrubber.

How does a Biological Scrubber work?

A biological scrubber utilizes tiny microorganisms (bacteria) to break down and digest contaminants. The bacteria feed on the contaminants and utilize this as a feed source to live and grow. When utilizing a biological scrubber for hydrogen sulfide (H2S) treatment, the by-product waste is acid from the digested H2S. This lowers the pH and requires the use of caustic to buffer the water and nutrient solution that is recirculated within the scrubber to maintain a neutral pH. The captured gas containing contaminants enters the bottom of a vertical biological scrubber. Similar to how the gas enters any other type of chemical scrubber or single or dual pass odor control scrubber.

The gas stream travels upward. Passes over a media bed that has been cultured to grow live microorganisms. A biological odor control scrubber already has “artificial intelligence” because of the millions of microbes colonies it supports.  

Topics: water treatment issues, odor control, advanced treatment solutions, biological scrubber, odor control scrubber, hydrogen sulfide (H2S), Chemical Odor, dissolved gases, wastewater, carbon dioxide, degasifier, gases, RO system, H2S Degasifier, what is a scrubber

Odor control and acid scrubbers are both popular in many industries.

Topics: odor control, water treatment, biological scrubber, odor control scrubber, hydrogen sulfide (H2S), Chemical Odor, dissolved gases, carbon dioxide, degasifier, gases, H2S Degasifier

The type of Odor Control Wet Scrubber selected for the treatment and neutralization of Ammonia (NH3) gases depends on several variables, including the type and source of the ammonia gas and whether or not it is “Free” ammonia and or unionized.

Ammonia is a very miscible and stable molecule with solid hydrogen bonds, making it very soluble in water and difficult to treat without using a properly designed and sized ammonia scrubber. The concentrations, air flow rates, temperature of the gas stream, and chemical reagents being utilized, such as caustic to remove and then treat the ammonia, all play a significant role in the removal efficiency of the ammonia gas scrubber system. Unlike other types of “odor control scrubbers,” an ammonia scrubber is much more sensitive to variables such as the gas stream temperature because of the solubility of ammonia.

Ammonia is produced from nitrogen and hydrogen 

the process is called the Haber Process by combining nitrogen with air and adding pressure, you can make ammonia.

It takes about 200 atmospheres of pressure, and the process varies from refinery to refinery. Still, on average, you can only make approximately 15% of ammonia during each pass which takes multiple passes to achieve the 15%. The reaction to make ammonia is exothermic when produced in a refining process. 

However, ammonia is also formed in nature in smaller quantities. Most ammonia (90%) is utilized for fertilizer production, but ammonia can be found in food, pharmaceutical products, and cleaning supplies. When ammonia gas is released into the air, it has a very noxious and pungent odor that can be dangerous to inhale, so often, odor control scrubbers are required to capture and treat the ammonia gas.

Topics: water treatment issues, water quality, degasification, pH levels of water, odor control, water treatment, advanced treatment solutions, biological scrubber, water plant, odor control scrubber, hydrogen sulfide (H2S), Chemical Odor, pH levels, Decarbonation, dissolved gases, wastewater, degasifier, gases, H2S Degasifier, Ammonia

In the United States manufacturing industry, an astonishing 400 million gallons of water per day (MGD) is consumed to generate steam.

Out of this amount, approximately 60 MGD is sent to blow-down drains, while another 300 MGD is used for direct injection of steam. The common denominator in all of these processes is the need for purified and treated water. Without proper treatment, manufacturers would face frequent shutdowns and increased capital expenditure, significantly impacting their cost of goods. One effective method of water treatment to protect boilers is through degasification and deaeration.

Degasification towers play a crucial role in removing harmful gases such as hydrogen sulfide (H2S), carbon dioxide (CO2), and often dissolved oxygen (DO). The elimination of these corrosive gases is vital for enhancing the lifespan and efficiency of boiler systems. If these gases are allowed to remain in the boiler feed water, particularly carbon dioxide (CO2), it can lead to disastrous consequences, including higher operating costs and reduced system longevity. Carbon dioxide (CO2) can convert into carbonic acid, creating a corrosive environment for the boiler and other critical components. In cases where an ion exchange process is implemented prior to the boiler, the presence of carbon dioxide (CO2) can drastically increase regeneration costs as the resins are consumed. By removing carbon dioxide (CO2), the life of the resin is extended, and the pH of the water is elevated, reducing the need for additional chemicals and further lowering operating costs.

Topics: water treatment issues, degasification, iron oxidation, water treatment, water distribution system, advanced treatment solutions, water plant, hydrogen sulfide (H2S), Decarbonation, ION Exchange Resin, feed water, De-Aeration, steam generation, steam generating boilers, carbon dioxide, steam, decarbonator, boiler system, degasifier, gases, RO membrane, carbonic acid, RO system, H2S Degasifier, Boiler feed water

Avoid problems with calcium chlorite and corrosive gasses with your odor control scrubber.

When planning or designing an odor control system, one should pay close attention to several key variables that can cause havoc on a chemical odor control scrubber when trying to treat hydrogen sulfide or ammonia gases. The need for odor control occurs in many different forms. It is essential to understand the process that is creating the odorous or corrosive gas and the need for odor control & air emissions treatment.

First, begin to identify

all the potential obstacles that may creep up later after the chemical odor or corrosive gas control system goes online, like acid or caustic consumption. For example, chemical odor control systems designed for water treatment for the municipal industry are typically needed and attached to a degasification or decarbonation process, often needed to treat hydrogen sulfide (H2S). However, designers often may not pay close enough attention to the type of water process available for “make-up” water for the chemical scrubber. The addition of caustic can create scaling or fouling. This unknown variable of the makeup water quality can lead to a complete tower shutdown if the chemical scrubber distribution and media bed scales or fouls. The most commonly used chemicals for a hydrogen sulfide (H2S) scrubber are either chlorine in the form of sodium hypochlorite or caustic in the form of caustic soda. Both of these chemicals are common to a water treatment facility and are already in place to adjust and control pH.

The makeup water plays a significant role in the operation of a chemical scrubber.

When water containing high hardness levels is used as the source for the makeup water, your chemical scrubber can become fouled, and scaling can occur in a matter of hours, depending on the alkalinity and salts within the water. Solidification can occur from the scaling when combining sodium hypochlorite and raw feed water at specific pH ranges and these ranges are usually the range needed to achieve peak performance. Calcium chloride will form, and your chemical odor control scrubber will become a solid chunk of calcium chlorite making, making the ability for water or air to pass freely through the media packing next to impossible. No matter what type of media packing is utilized in the odor control or gas scrubber, it can foul and scale if the water chemistry is incorrect.  Trust me when I say “been there and done that”!  I have seen operators who have allowed a chemical scrubber to become out of balance with pH control and completely solidify the tower column to the degree that neither air nor water passage is possible. The problem can still occur with ammonia scrubbers but are different with different sets of parameters.

Topics: odor control, water treatment, advanced treatment solutions, biological scrubber, water plant, odor control scrubber, hydrogen sulfide (H2S), calcium carbonate, media packing, pH levels, Alkalinity, Langilier index (LSI), scaling, chlorine, caustic, ION Exchange Resin, Safe drinking water, dissolved gases, De-Aeration, carbon dioxide, oxygen, degasifier, gases, H2S Degasifier, calcium chlorite